Thrombophlebitis - usually manifests with erythema, inflammation, and/or pain at the IV site (think about changing the IV q3 days to help prevent this)
Infiltration - this happens when whatever you are giving through the IV (meds/fluids) starts to leak into the surrounding tissue (this can cause a big problem - compartment syndrome - if the volume is large enough)
Blockage - something, a blood clot for example, can clog the IV making it unusable (flushes can help minimize the risk of this)
Air embolus
Source: Step up to Medicine 2nd ED Agabegi and Agabegi
Pic source: http://en.wikipedia.org/wiki/Intravenous_therapy
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